| Date | Home | Away | Result |
|---|---|---|---|
| 16/05/14 20:00 | FC Malaga | UD Levante | 1-0 |
| 17/05/14 15:00 | Real Madrid | Espanyol Barcelona | 3-1 |
| 17/05/14 17:00 | FC Barcelona | Atletico Madrid | 1-1 |
| 17/05/14 21:00 | FC Valencia | Celta Vigo | 2-1 |
| 18/05/14 11:00 | Real Sociedad | FC Villarreal | 1-2 |
| 18/05/14 17:00 | Real Valladolid | FC Granada | 0-1 |
| 18/05/14 17:00 | CA Osasuna | Real Betis Sevilla | 2-1 |
| 18/05/14 17:00 | UD Almeria | Athletic Bilbao | 0-0 |
| 18/05/14 17:00 | Rayo Vallecano | FC Getafe | 1-2 |
| 18/05/14 20:00 | FC Sevilla | FC Elche | 3-1 |