| Date | Home | Away | Result |
|---|---|---|---|
| 12/05/12 19:00 | Real Sociedad | FC Valencia | 1-0 |
| 12/05/12 21:00 | Real Betis Sevilla | FC Barcelona | 2-2 |
| 13/05/12 19:00 | FC Villarreal | Atletico Madrid | 0-1 |
| 13/05/12 19:00 | FC Malaga | Sporting Gijon | 1-0 |
| 13/05/12 19:00 | Racing Santander | CA Osasuna | 2-4 |
| 13/05/12 19:00 | UD Levante | Athletic Bilbao | 3-0 |
| 13/05/12 19:00 | Real Madrid | RCD Mallorca | 4-1 |
| 13/05/12 19:00 | Espanyol Barcelona | FC Sevilla | 1-1 |
| 13/05/12 19:00 | Rayo Vallecano | FC Granada | 1-0 |
| 13/05/12 19:00 | FC Getafe | Real Saragossa | 0-2 |