| Date | Home | Away | Result |
|---|---|---|---|
| 19/07/20 16:00 | Deportivo Alaves | FC Barcelona | 0-5 |
| 19/07/20 17:30 | Real Valladolid | Real Betis Sevilla | 2-0 |
| 19/07/20 17:30 | FC Villarreal | SD Eibar | 4-0 |
| 19/07/20 20:00 | Espanyol Barcelona | Celta Vigo | 0-0 |
| 19/07/20 20:00 | FC Sevilla | FC Valencia | 1-0 |
| 19/07/20 20:00 | CD Leganes | Real Madrid | 2-2 |
| 19/07/20 20:00 | FC Granada | Athletic Bilbao | 4-0 |
| 19/07/20 20:00 | Atletico Madrid | Real Sociedad | 1-1 |
| 19/07/20 20:00 | CA Osasuna | RCD Mallorca | 2-2 |
| 19/07/20 20:00 | UD Levante | FC Getafe | 1-0 |