| Date | Home | Away | Result |
|---|---|---|---|
| 01/06/13 16:00 | Real Madrid | CA Osasuna | 4-2 |
| 01/06/13 18:00 | FC Barcelona | FC Malaga | 4-1 |
| 01/06/13 20:00 | UD Levante | Real Betis Sevilla | 1-1 |
| 01/06/13 20:00 | Deportivo La Coruna | Real Sociedad | 0-1 |
| 01/06/13 20:00 | Rayo Vallecano | Athletic Bilbao | 2-2 |
| 01/06/13 20:00 | RCD Mallorca | Real Valladolid | 4-2 |
| 01/06/13 20:00 | Celta Vigo | Espanyol Barcelona | 1-0 |
| 01/06/13 20:00 | Real Saragossa | Atletico Madrid | 1-3 |
| 01/06/13 20:00 | FC Granada | FC Getafe | 2-0 |
| 01/06/13 20:00 | FC Sevilla | FC Valencia | 4-3 |