| Date | Home | Away | Result |
|---|---|---|---|
| 17/05/14 19:45 | Udinese Calcio | Sampdoria Genua | 3-3 |
| 18/05/14 14:00 | Juventus Turin | Cagliari Calcio | 3-0 |
| 18/05/14 14:00 | Catania Calcio | Atalanta Bergamo | 2-1 |
| 18/05/14 14:00 | FC Genua 1893 | AS Roma | 1-0 |
| 18/05/14 19:45 | Fiorentina | FC Turin | 2-2 |
| 18/05/14 19:45 | AC Milan | Sassuolo Calcio | 2-1 |
| 18/05/14 19:45 | SSC Napoli | Hellas Verona | 5-1 |
| 18/05/14 19:45 | AC Chievo Verona | Inter Milan | 2-1 |
| 18/05/14 19:45 | Lazio Rom | FC Bologna | 1-0 |
| 18/05/14 19:45 | Parma Calcio 1913 | AS Livorno | 2-0 |