| Date | Home | Away | Result |
|---|---|---|---|
| 18/05/13 19:45 | Sampdoria Genua | Juventus Turin | 3-2 |
| 19/05/13 14:00 | Atalanta Bergamo | AC Chievo Verona | 2-2 |
| 19/05/13 14:00 | FC Bologna | FC Genua 1893 | 0-0 |
| 19/05/13 19:45 | Pescara Calcio | Fiorentina | 1-5 |
| 19/05/13 19:45 | FC Turin | Catania Calcio | 2-2 |
| 19/05/13 19:45 | Cagliari Calcio | Lazio Rom | 1-0 |
| 19/05/13 19:45 | Inter Milan | Udinese Calcio | 2-5 |
| 19/05/13 19:45 | US Palermo | Parma Calcio 1913 | 1-3 |
| 19/05/13 19:45 | AC Siena | AC Milan | 1-2 |
| 19/05/13 19:45 | AS Roma | SSC Napoli | 2-1 |