| Date | Dead line | Home | Away | Result | Points rule |
|---|---|---|---|---|---|
| 14/10/22 20:00 | 14/10/22 20:00 | Rayo Vallecano | FC Getafe | 0-0 | 2 - 4 points |
| 15/10/22 13:00 | 15/10/22 13:00 | FC Girona | FC Cadiz | 1-1 | 2 - 4 points |
| 15/10/22 15:15 | 15/10/22 15:15 | FC Valencia | FC Elche | 2-2 | 2 - 4 points |
| 15/10/22 17:30 | 15/10/22 17:30 | RCD Mallorca | FC Sevilla | 0-1 | 2 - 4 points |
| 15/10/22 20:00 | 15/10/22 20:00 | Athletic Bilbao | Atletico Madrid | 0-1 | 2 - 4 points |
| 16/10/22 13:00 | 16/10/22 13:00 | Celta Vigo | Real Sociedad | 1-2 | 2 - 4 points |
| 16/10/22 15:15 | 16/10/22 15:15 | Real Madrid | FC Barcelona | 3-1 | 2 - 4 points |
| 16/10/22 17:30 | 16/10/22 17:30 | Espanyol Barcelona | Real Valladolid | 1-0 | 2 - 4 points |
| 16/10/22 20:00 | 16/10/22 20:00 | Real Betis Sevilla | UD Almeria | 3-1 | 2 - 4 points |
| 17/10/22 20:00 | 17/10/22 20:00 | FC Villarreal | CA Osasuna | 2-0 | 2 - 4 points |