| Date | Dead line | Home | Away | Result | Points rule |
|---|---|---|---|---|---|
| 07/10/22 20:00 | 07/10/22 20:00 | CA Osasuna | FC Valencia | 1-2 | 2 - 4 points |
| 08/10/22 13:00 | 08/10/22 13:00 | UD Almeria | Rayo Vallecano | 3-1 | 2 - 4 points |
| 08/10/22 15:15 | 08/10/22 15:15 | Atletico Madrid | FC Girona | 2-1 | 2 - 4 points |
| 08/10/22 17:30 | 08/10/22 17:30 | FC Sevilla | Athletic Bilbao | 1-1 | 2 - 4 points |
| 08/10/22 20:00 | 08/10/22 20:00 | FC Getafe | Real Madrid | 0-1 | 2 - 4 points |
| 09/10/22 13:00 | 09/10/22 13:00 | Real Valladolid | Real Betis Sevilla | 0-0 | 2 - 4 points |
| 09/10/22 15:15 | 09/10/22 15:15 | FC Cadiz | Espanyol Barcelona | 2-2 | 2 - 4 points |
| 09/10/22 17:30 | 09/10/22 17:30 | Real Sociedad | FC Villarreal | 1-0 | 2 - 4 points |
| 09/10/22 20:00 | 09/10/22 20:00 | FC Barcelona | Celta Vigo | 1-0 | 2 - 4 points |
| 10/10/22 20:30 | 10/10/22 20:30 | FC Elche | RCD Mallorca | 1-1 | 2 - 4 points |