| Date | Dead line | Home | Away | Result | Points rule |
|---|---|---|---|---|---|
| 30/09/22 20:00 | 30/09/22 20:00 | Athletic Bilbao | UD Almeria | 4-0 | 2 - 4 points |
| 01/10/22 13:00 | 01/10/22 13:00 | FC Cadiz | FC Villarreal | 0-0 | 2 - 4 points |
| 01/10/22 15:15 | 01/10/22 15:15 | FC Getafe | Real Valladolid | 2-3 | 2 - 4 points |
| 01/10/22 17:30 | 01/10/22 17:30 | FC Sevilla | Atletico Madrid | 0-2 | 2 - 4 points |
| 01/10/22 20:00 | 01/10/22 20:00 | RCD Mallorca | FC Barcelona | 0-1 | 2 - 4 points |
| 02/10/22 13:00 | 02/10/22 13:00 | Espanyol Barcelona | FC Valencia | 2-2 | 2 - 4 points |
| 02/10/22 15:15 | 02/10/22 15:15 | Celta Vigo | Real Betis Sevilla | 1-0 | 2 - 4 points |
| 02/10/22 17:30 | 02/10/22 17:30 | FC Girona | Real Sociedad | 3-5 | 2 - 4 points |
| 02/10/22 20:00 | 02/10/22 20:00 | Real Madrid | CA Osasuna | 1-1 | 2 - 4 points |
| 03/10/22 20:00 | 03/10/22 20:00 | Rayo Vallecano | FC Elche | 2-1 | 2 - 4 points |