| Date | Dead line | Home | Away | Result | Points rule |
|---|---|---|---|---|---|
| 16/09/22 20:00 | 16/09/22 20:00 | Real Valladolid | FC Cadiz | 0-1 | 2 - 4 points |
| 17/09/22 13:00 | 17/09/22 13:00 | RCD Mallorca | UD Almeria | 1-0 | 2 - 4 points |
| 17/09/22 15:15 | 17/09/22 15:15 | FC Barcelona | FC Elche | 3-0 | 2 - 4 points |
| 17/09/22 17:30 | 17/09/22 17:30 | FC Valencia | Celta Vigo | 3-0 | 2 - 4 points |
| 17/09/22 20:00 | 17/09/22 20:00 | Athletic Bilbao | Rayo Vallecano | 3-2 | 2 - 4 points |
| 18/09/22 13:00 | 18/09/22 13:00 | CA Osasuna | FC Getafe | 0-2 | 2 - 4 points |
| 18/09/22 15:15 | 18/09/22 15:15 | FC Villarreal | FC Sevilla | 1-1 | 2 - 4 points |
| 18/09/22 17:30 | 18/09/22 17:30 | Real Sociedad | Espanyol Barcelona | 2-1 | 2 - 4 points |
| 18/09/22 17:30 | 18/09/22 17:30 | Real Betis Sevilla | FC Girona | 2-1 | 2 - 4 points |
| 18/09/22 20:00 | 18/09/22 20:00 | Atletico Madrid | Real Madrid | 1-2 | 2 - 4 points |