| Date | Dead line | Home | Away | Result | Points rule |
|---|---|---|---|---|---|
| 09/09/22 20:00 | 09/09/22 20:00 | FC Girona | Real Valladolid | 2-1 | 2 - 4 points |
| 10/09/22 13:00 | 10/09/22 13:00 | Rayo Vallecano | FC Valencia | 2-1 | 2 - 4 points |
| 10/09/22 15:15 | 10/09/22 15:15 | Espanyol Barcelona | FC Sevilla | 2-3 | 2 - 4 points |
| 10/09/22 17:30 | 10/09/22 17:30 | FC Cadiz | FC Barcelona | 0-4 | 2 - 4 points |
| 10/09/22 20:00 | 10/09/22 20:00 | Atletico Madrid | Celta Vigo | 4-1 | 2 - 4 points |
| 11/09/22 13:00 | 11/09/22 13:00 | Real Madrid | RCD Mallorca | 4-1 | 2 - 4 points |
| 11/09/22 15:15 | 11/09/22 15:15 | FC Elche | Athletic Bilbao | 1-4 | 2 - 4 points |
| 11/09/22 17:30 | 11/09/22 17:30 | FC Getafe | Real Sociedad | 2-1 | 2 - 4 points |
| 11/09/22 20:00 | 11/09/22 20:00 | Real Betis Sevilla | FC Villarreal | 1-0 | 2 - 4 points |
| 12/09/22 20:00 | 12/09/22 20:00 | UD Almeria | CA Osasuna | 0-1 | 2 - 4 points |