| Date | Dead line | Home | Away | Result | Points rule |
|---|---|---|---|---|---|
| 25/08/23 18:30 | 25/08/23 18:30 | UD Las Palmas | Real Sociedad | 0-0 | 2 - 4 points |
| 25/08/23 20:30 | 25/08/23 20:30 | Celta Vigo | Real Madrid | 0-1 | 2 - 4 points |
| 26/08/23 18:00 | 26/08/23 18:00 | FC Cadiz | UD Almeria | 1-1 | 2 - 4 points |
| 26/08/23 18:30 | 26/08/23 18:30 | FC Granada | RCD Mallorca | 3-2 | 2 - 4 points |
| 26/08/23 20:30 | 26/08/23 20:30 | FC Sevilla | FC Girona | 1-2 | 2 - 4 points |
| 27/08/23 16:30 | 27/08/23 16:30 | FC Villarreal | FC Barcelona | 3-4 | 2 - 4 points |
| 27/08/23 18:30 | 27/08/23 18:30 | FC Valencia | CA Osasuna | 1-2 | 2 - 4 points |
| 27/08/23 20:30 | 27/08/23 20:30 | Athletic Bilbao | Real Betis Sevilla | 4-2 | 2 - 4 points |
| 28/08/23 18:30 | 28/08/23 18:30 | FC Getafe | Deportivo Alaves | 1-0 | 2 - 4 points |
| 28/08/23 20:30 | 28/08/23 20:30 | Rayo Vallecano | Atletico Madrid | 0-7 | 2 - 4 points |