| Date | Dead line | Home | Away | Result | Points rule |
|---|---|---|---|---|---|
| 26/08/22 19:00 | 26/08/22 19:00 | FC Girona | Celta Vigo | 0-1 | 2 - 4 points |
| 26/08/22 21:00 | 26/08/22 21:00 | Real Betis Sevilla | CA Osasuna | 1-0 | 2 - 4 points |
| 27/08/22 16:30 | 27/08/22 16:30 | FC Elche | Real Sociedad | 0-1 | 2 - 4 points |
| 27/08/22 18:30 | 27/08/22 18:30 | Rayo Vallecano | RCD Mallorca | 0-2 | 2 - 4 points |
| 27/08/22 21:00 | 27/08/22 21:00 | UD Almeria | FC Sevilla | 2-1 | 2 - 4 points |
| 28/08/22 16:30 | 28/08/22 16:30 | FC Getafe | FC Villarreal | 0-0 | 2 - 4 points |
| 28/08/22 18:30 | 28/08/22 18:30 | FC Barcelona | Real Valladolid | 4-0 | 2 - 4 points |
| 28/08/22 21:00 | 28/08/22 21:00 | Espanyol Barcelona | Real Madrid | 1-3 | 2 - 4 points |
| 29/08/22 19:00 | 29/08/22 19:00 | FC Cadiz | Athletic Bilbao | 0-4 | 2 - 4 points |
| 29/08/22 21:00 | 29/08/22 21:00 | FC Valencia | Atletico Madrid | 0-1 | 2 - 4 points |