| Date | Dead line | Home | Away | Result | Points rule |
|---|---|---|---|---|---|
| 18/08/23 18:30 | 18/08/23 18:30 | RCD Mallorca | FC Villarreal | 0-1 | 2 - 4 points |
| 18/08/23 20:30 | 18/08/23 20:30 | FC Valencia | UD Las Palmas | 1-0 | 2 - 4 points |
| 19/08/23 16:00 | 19/08/23 16:00 | Real Sociedad | Celta Vigo | 1-1 | 2 - 4 points |
| 19/08/23 18:30 | 19/08/23 18:30 | UD Almeria | Real Madrid | 1-3 | 2 - 4 points |
| 19/08/23 20:30 | 19/08/23 20:30 | CA Osasuna | Athletic Bilbao | 0-2 | 2 - 4 points |
| 20/08/23 18:00 | 20/08/23 18:00 | FC Girona | FC Getafe | 3-0 | 2 - 4 points |
| 20/08/23 18:30 | 20/08/23 18:30 | FC Barcelona | FC Cadiz | 2-0 | 2 - 4 points |
| 20/08/23 20:30 | 20/08/23 20:30 | Real Betis Sevilla | Atletico Madrid | 0-0 | 2 - 4 points |
| 21/08/23 18:00 | 21/08/23 18:00 | Deportivo Alaves | FC Sevilla | 4-3 | 2 - 4 points |
| 21/08/23 20:30 | 21/08/23 20:30 | FC Granada | Rayo Vallecano | 0-2 | 2 - 4 points |