| Date | Dead line | Home | Away | Result | Points rule |
|---|---|---|---|---|---|
| 19/08/22 19:00 | 19/08/22 19:00 | Espanyol Barcelona | Rayo Vallecano | 0-2 | 2 - 4 points |
| 19/08/22 21:00 | 19/08/22 21:00 | FC Sevilla | Real Valladolid | 1-1 | 2 - 4 points |
| 20/08/22 16:30 | 20/08/22 16:30 | CA Osasuna | FC Cadiz | 2-0 | 2 - 4 points |
| 20/08/22 18:30 | 20/08/22 18:30 | RCD Mallorca | Real Betis Sevilla | 1-2 | 2 - 4 points |
| 20/08/22 21:00 | 20/08/22 21:00 | Celta Vigo | Real Madrid | 1-4 | 2 - 4 points |
| 21/08/22 16:30 | 21/08/22 16:30 | Athletic Bilbao | FC Valencia | 1-0 | 2 - 4 points |
| 21/08/22 18:30 | 21/08/22 18:30 | Atletico Madrid | FC Villarreal | 0-2 | 2 - 4 points |
| 21/08/22 21:00 | 21/08/22 21:00 | Real Sociedad | FC Barcelona | 1-4 | 2 - 4 points |
| 22/08/22 19:00 | 22/08/22 19:00 | FC Elche | UD Almeria | 1-1 | 2 - 4 points |
| 22/08/22 21:00 | 22/08/22 21:00 | FC Girona | FC Getafe | 3-1 | 2 - 4 points |