| Date | Dead line | Home | Away | Result | Points rule |
|---|---|---|---|---|---|
| 28/10/22 20:00 | 28/10/22 20:00 | RCD Mallorca | Espanyol Barcelona | 1-1 | 2 - 4 points |
| 29/10/22 13:00 | 29/10/22 13:00 | UD Almeria | Celta Vigo | 3-1 | 2 - 4 points |
| 29/10/22 15:15 | 29/10/22 15:15 | FC Cadiz | Atletico Madrid | 3-2 | 2 - 4 points |
| 29/10/22 17:30 | 29/10/22 17:30 | FC Sevilla | Rayo Vallecano | 0-1 | 2 - 4 points |
| 29/10/22 20:00 | 29/10/22 20:00 | FC Valencia | FC Barcelona | 0-1 | 2 - 4 points |
| 30/10/22 13:00 | 30/10/22 13:00 | CA Osasuna | Real Valladolid | 2-0 | 2 - 4 points |
| 30/10/22 15:15 | 30/10/22 15:15 | Real Madrid | FC Girona | 1-1 | 2 - 4 points |
| 30/10/22 17:30 | 30/10/22 17:30 | Athletic Bilbao | FC Villarreal | 1-0 | 2 - 4 points |
| 30/10/22 20:00 | 30/10/22 20:00 | Real Sociedad | Real Betis Sevilla | 0-2 | 2 - 4 points |
| 31/10/22 20:00 | 31/10/22 20:00 | FC Elche | FC Getafe | 0-1 | 2 - 4 points |