| Date | Dead line | Home | Away | Result | Points rule |
|---|---|---|---|---|---|
| 22/10/22 13:00 | 22/10/22 13:00 | Rayo Vallecano | FC Cadiz | 5-1 | 2 - 4 points |
| 22/10/22 15:15 | 22/10/22 15:15 | Real Valladolid | Real Sociedad | 1-0 | 2 - 4 points |
| 22/10/22 17:30 | 22/10/22 17:30 | FC Valencia | RCD Mallorca | 1-2 | 2 - 4 points |
| 22/10/22 20:00 | 22/10/22 20:00 | Real Madrid | FC Sevilla | 3-1 | 2 - 4 points |
| 23/10/22 13:00 | 23/10/22 13:00 | Espanyol Barcelona | FC Elche | 2-2 | 2 - 4 points |
| 23/10/22 15:15 | 23/10/22 15:15 | Real Betis Sevilla | Atletico Madrid | 1-2 | 2 - 4 points |
| 23/10/22 17:30 | 23/10/22 17:30 | FC Girona | CA Osasuna | 1-1 | 2 - 4 points |
| 23/10/22 17:30 | 23/10/22 17:30 | FC Villarreal | UD Almeria | 2-1 | 2 - 4 points |
| 23/10/22 20:00 | 23/10/22 20:00 | FC Barcelona | Athletic Bilbao | 4-0 | 2 - 4 points |
| 24/10/22 20:00 | 24/10/22 20:00 | Celta Vigo | FC Getafe | 1-1 | 2 - 4 points |