| Date | Dead line | Home | Away | Result | Points rule |
|---|---|---|---|---|---|
| 18/10/22 18:00 | 18/10/22 18:00 | FC Sevilla | FC Valencia | 1-1 | 2 - 4 points |
| 18/10/22 19:00 | 18/10/22 19:00 | FC Getafe | Athletic Bilbao | 2-2 | 2 - 4 points |
| 18/10/22 20:00 | 18/10/22 20:00 | Atletico Madrid | Rayo Vallecano | 1-1 | 2 - 4 points |
| 19/10/22 18:00 | 19/10/22 18:00 | FC Cadiz | Real Betis Sevilla | 0-0 | 2 - 4 points |
| 19/10/22 18:00 | 19/10/22 18:00 | Real Valladolid | Celta Vigo | 4-1 | 2 - 4 points |
| 19/10/22 19:00 | 19/10/22 19:00 | Real Sociedad | RCD Mallorca | 1-0 | 2 - 4 points |
| 19/10/22 20:00 | 19/10/22 20:00 | FC Elche | Real Madrid | 0-3 | 2 - 4 points |
| 20/10/22 18:00 | 20/10/22 18:00 | UD Almeria | FC Girona | 3-2 | 2 - 4 points |
| 20/10/22 19:00 | 20/10/22 19:00 | CA Osasuna | Espanyol Barcelona | 1-0 | 2 - 4 points |
| 20/10/22 20:00 | 20/10/22 20:00 | FC Barcelona | FC Villarreal | 3-0 | 2 - 4 points |