| Date | Dead line | Home | Away | Result | Points rule |
|---|---|---|---|---|---|
| 12/08/22 20:00 | 12/08/22 20:00 | CA Osasuna | FC Sevilla | 2-1 | 2 - 4 points |
| 13/08/22 16:00 | 13/08/22 16:00 | Celta Vigo | Espanyol Barcelona | 2-2 | 2 - 4 points |
| 13/08/22 18:00 | 13/08/22 18:00 | Real Valladolid | FC Villarreal | 0-3 | 2 - 4 points |
| 13/08/22 20:00 | 13/08/22 20:00 | FC Barcelona | Rayo Vallecano | 0-0 | 2 - 4 points |
| 14/08/22 16:30 | 14/08/22 16:30 | FC Cadiz | Real Sociedad | 0-1 | 2 - 4 points |
| 14/08/22 18:30 | 14/08/22 18:30 | FC Valencia | FC Girona | 1-0 | 2 - 4 points |
| 14/08/22 21:00 | 14/08/22 21:00 | UD Almeria | Real Madrid | 1-2 | 2 - 4 points |
| 15/08/22 16:30 | 15/08/22 16:30 | Athletic Bilbao | RCD Mallorca | 0-0 | 2 - 4 points |
| 15/08/22 18:30 | 15/08/22 18:30 | FC Getafe | Atletico Madrid | 0-3 | 2 - 4 points |
| 15/08/22 20:30 | 15/08/22 20:30 | Real Betis Sevilla | FC Elche | 3-0 | 2 - 4 points |