Schedule
| Date | Dead line | Home | Away | Result | Points rule |
|---|---|---|---|---|---|
| 16/02/23 17:45 | 16/02/23 17:45 | Ajax Amsterdam | 1. FC Union Berlin | 0-0 | 2 - 4 points |
| 16/02/23 17:45 | 16/02/23 17:45 | FC Red Bull Salzburg | AS Roma | 1-0 | 2 - 4 points |
| 16/02/23 17:45 | 16/02/23 17:45 | FC Barcelona | Manchester United | 2-2 | 2 - 4 points |
| 16/02/23 17:45 | 16/02/23 17:45 | Schachtjor Donezk | Stade Rennes | 2-1 | 2 - 4 points |
| 16/02/23 20:00 | 16/02/23 20:00 | Bayer 04 Leverkusen | AS Monaco | 2-3 | 2 - 4 points |
| 16/02/23 20:00 | 16/02/23 20:00 | FC Sevilla | PSV Eindhoven | 3-0 | 2 - 4 points |
| 16/02/23 20:00 | 16/02/23 20:00 | Juventus Turin | FC Nantes | 1-1 | 2 - 4 points |
| 16/02/23 20:00 | 16/02/23 20:00 | Sporting Lisbon | FC Midtjylland | 1-1 | 2 - 4 points |